Crystal Structure of (2,2'-Bipyridine-N,N')(2,2',2"-Triaminotriethylamine-N,N',N",N''')nickel(II) Diperchiorate
نویسندگان
چکیده
منابع مشابه
The hydrothermal synthesis and X-ray crystal structure of Ag (1)-4, 4"-bipyridine-based coordination polymer
Hydrothermal synthetic were studied for the preparation of coordination polymeric material basedon Ag (I) and 4, 4"-bipy. A polymeric compound [Ag (4, 4'-bipy)].NO3. (I), was prepared andstructurally characterized by single crystal X-ray diffraction. Compound 1(91% yield) was isolatedfrom the reaction of AgNO3 with 4, 41bipy in 2:1 molar ratio. In compound I. each silver (I) islinked to two nit...
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A new binuclear complex of [{NiCl(6-mbipy)}2(μ-Cl)2] (1) was prepared from the reaction of NiCl2.6H2O and 6-methyl-2,2'-bipyridine (6-mbipy) in a mixture of methanol and acetonitrile. Suitable crystals of 1 for X-ray diffraction measurement were obtained by slow evaporation of the resulted green solution at room ...
متن کاملCrystal structure of 4,4′-(disulfanediyl)dibutanoic acid–4,4′-bipyridine (1/1)
4,4'-(Disulfanediyl)dibutanoic acid (dtba) and 4,4'-bipyridine (4,4'-bpy) crystallize in an 1:1 ratio, leading to the title co-crystal with composition C8H14O4S2·C10H8N2. A distinctive feature of the crystal structure is the geometry of the dtba moiety, which appears to be stretched [with a 9.98 (1) Å span between outermost carbons] and acts as an hydrogen-bonding connector, forming linear chai...
متن کاملCrystal structure of (2,2'-bipyridine-N,N')(1,4,7,10-tetraazacyclododecane-N,N',N",N''')nickel(II) diperchlorate.
ligands have been widely investigated in fundamental and applied science.1 In the present paper, we report on the crystal structure of the Ni(II) complex which contains the tetraaza macrocyclic ligand, to expand knowledge in this area. The ligand 1,4,7,10-tetraazacyclododecane (cyclen) was prepared according to the literature.2 Equimolar quantities of nickel perchlorate hexahydrate and the liga...
متن کاملThe crystal structure of non-modified and bipyridine-modified PNA duplexes.
Peptide nucleic acid (PNA) is a synthetic analogue of DNA that commonly has an N-aminoethyl glycine backbone. The crystal structures of two PNA duplexes, one containing eight standard nucleobase pairs (GGCATGCC)(2), and the other containing the same nucleobase pairs and a central pair of bipyridine ligands, have been solved with a resolution of 1.22 and 1.10 Å, respectively. The non-modified PN...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 2003
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.19.641